PBT弹性体微相分离及对其力学性能的影响研究

为了获得微相分离对宽温PBT叠氮聚醚弹性体力学性能的影响规律,用红外光谱分析法(FT-IR)和动态热力学分析法(DMA)研究了PBT叠氮聚醚弹性体产生微相分离的机理和影响因素。用调节硬段含量、交联参数的方法调控其微相分离,控制适当的微相分离程度可显著改善推进剂的力学性能。研究结果表明:在二元醇扩链的弹性体体系中,当硬段含量约为15%时,弹性体发生相对最大比例的微相分离,体现出较佳的综合力学性能。通过微相分离的调控可获得宽温范围内综合力学性能较好的叠氮聚醚推进剂用粘合剂基体材料。     

超细CL‑20的可控批量制备及降感技术

为了批量制备低感度超细六硝基六氮杂异伍兹烷(CL-20),用作固体推进剂的高能添加剂,以氧化锆球(0.8 mm或0.3 mm)为研磨介质,采用HLG-05型粉碎设备制备了两种超细类球形CL-20。用激光粒度仪、扫描电子显微镜(SEM)、X射线衍射(XRD)、傅里叶红外光谱(FTIR)和拉曼光谱(Raman)对CL-20样品进行了相应的表征;用差示扫描量热(DSC)研究了样品的热分解性能;测试了样品的撞击、摩擦和静电火花感度。结果表明:制备的微米级和亚微米级CL-20平均粒径分别为3.43μm和320 nm,表面光滑,类球形;其晶型不变,无质杂峰;超细CL-20的分解峰温稍有下降,活化能降低,其静电火花感度略有提高,但撞击感度分别降低了24.6%和108.4%,摩擦感度下降了8%和20%;机械感度降低效果明显,在高能固体推进剂中有较大的应用前景。     

吸气式电推进系统可行条件分析

吸气式电推进系统作为有可能实现长寿命超低轨飞行的技术而被关注。根据不同轨道环境条件，采用管状结构进气道、以及机械增压的吸气方式，讨论了吸气式电推进系统所需的可行条件。分析表明，在轨高度180~240km，航天器所需总功耗与迎风面之比需要大于2kW/m2，电推力器比冲需大于4×104m/s，方可满足推阻平衡需求。分析得出，实现吸气式系统在地球轨道的运用，关键技术在于增加气体收集效率并且降低收集功耗，同时电推力器的效率还需进一步提升。     

热/力耦合作用下基于应力分析的冰破坏准则

根据飞机热除冰的物理过程,考虑外部空气动力和蒙皮表面加热的作用,建立了NACA 0012翼型前缘冰层应力计算模型。采用有限元方法和平面三角形单元对控制方程组进行了求解,获得了外部空气动力和蒙皮表面加热对冰层黏附界面应力的影响规律。研究表明:蒙皮表面不加热时,来流速度影响了黏附界面应力的强度,来流攻角影响了黏附界面应力的分布,冰-蒙皮间黏附界面切应力最大值随来流速度呈近似线性增大趋势,但外部空气动力很难造成冰层破坏。蒙皮表面加热时,冰-蒙皮间黏附界面的耦合应力和冰层内部的主应力随着热流密度的增大而增大,很容易超过剪切强度,这是造成冰破坏的关键因素。耦合冰-蒙皮剪切强度随界面温度的变化关系,初步建立了基于应力分析和热/力耦合作用的冰破坏判断准则。外部空气动力产生的界面应力和蒙皮表面加热产生的界面热应力之和，必须大于与蒙皮表面温度相关的剪切强度，则冰层发生破坏，破坏位置是耦合应力超过剪切强度的区域。      

The adjusted optical properties for Galileo/BeiDou-2/QZS-1 satellites and initial results on BeiDou-3e and QZS-2 satellites

Solar Radiation Pressure (SRP) is the dominant non-gravitational perturbation for GNSS (Global Navigation Satellite System) satellites. In the absence of precise surface models, the Empirical CODE Orbit Models (ECOM, ECOM2) are widely used in GNSS satellite orbit determination. Based on previous studies, the use of an a priori box-wing model enhances the ECOM model, especially if the spacecraft is a stretched body satellite. However, so far not all the GNSS system providers have published their metadata. To ensure a precise use of the a priori box-wing model, we estimate the optical parameters of all the Galileo, BeiDou-2, and QZS-1 (Quasi Zenith Satellite System) satellites based on the physical processes from SRP to acceleration. Validation using orbit prediction proves that the adjusted parameters of Galileo and QZS-1 satellites exhibit almost the same performance as the corresponding published and “best guess” values. Whereas, the estimated parameters of BeiDou-2 satellites demonstrate an improvement of more than 60% over the initial “guess” values. The resulting optical parameters of all the satellites are introduced into an a priori box-wing model, which is jointly used with ECOM and ECOM2 model in the orbit determination. Results show that the pure ECOM2 model exhibits better performance than the pure ECOM model for Galileo, BeiDou-2 GEO and QZS-1 orbits. Combined with the a priori box-wing model the ECOM model (ECOM+BW) results in the best Galileo, BeiDou-2 GEO and QZS-1 orbits. The standard deviation (STD) of satellite laser ranging residuals reduce by about 20% and 5% with respect to the pure ECOM2 model for Galileo and BeiDou-2 GEO orbits, while the reductions are about 40% and 60% for QZS-1 orbits in yaw-steering and orbit-normal mode respectively. BeiDou-2 IGSO and MEO satellite orbits do not benefit much from the a priori box-wing model. In summary, we suggest setting up a unified SRP model of ECOM+BW for Galileo, QZS-1, and BeiDou-2 orbits based on the adjusted metadata. In addition, we estimate the optical parameters of BeiDou-3e and QZS-2 satellites using a limited number of tracking stations. Results regarding the unified SRP model indicate the same advantages, the STD of satellite laser ranging residuals reduces by about 30% and 20% for QZS-2 and BeiDou-3e orbits respectively over orbit products without a priori model. The estimation procedure is effective and easy to apply to the new emerging satellites in the future.     

Microstructure,porosity and mechanical properties of selective laser melted AlSi10Mg

Finite element modeling (FEM), microscopy, X-ray computed tomography (CT) and mechanical property tests were used to study the microstructure, porosity and mechanical properties of an AlSi10Mg alloy produced by selective laser melting (SLM). The simulation of the melt pool and thermal history under different energy densities produced an optimized result with an energy density of 44.5 J·mm⁻³. The high cooling rate during the SLM process significantly refined the previous α-Al dendrites. The growth direction of the network-like Al-Si eutectic structure at different orientations confirmed the anisotropic nature of the microstructure. Furthermore, the microhardness, tensile testing and fracture analysis results proved that there were no obvious distinctions in the strength between the transverse and longitudinal directions, and that the ductility was anisotropic, possibly due to the shape and distribution of the pores. The pores measured by X-ray CT at different energy densities confirmed that the sphericity of the pores was inversely related to pores volumes. With optimized processing conditions, the porosity of the selective laser melted sample decreased leading to the improved fabricated fuel system component via SLM.     

热发射过程中发射箱蒙皮力学性能损伤与试验研究

文中选择大、中、小3种典型结构尺寸的发射箱，利用计算流体动力学（Computational fluid dynamics，CFD）仿真软件Fluent对发射箱蒙皮表面在导弹发射过程中的力、热环境进行了仿真分析。以铝合金材料为例，对发射箱蒙皮材料在燃气流环境中力学性能损伤情况进行了烧蚀试验研究。研究结果表明，随着烧蚀时间延长，铝合金材料力学性能损伤存在一个突变点，在1.5 s内下降不明显，但是当烧蚀时间延长至2.0 s时，力学性能急剧下降至0。该研究结果为铝合金发射箱轻量化设计、热防护设计和使用次数设计等提供了数据支撑。     

航空电连接器力学性能和电学性能仿真

电连接器作为飞机上重要的元件,电连接器的安全工作已经是飞机安全的生命线。针对提高电连接器可靠性的要求,研究了航空电连接器的力学性能和电学性能。通过ANSYS Workbench的静力学模块对插拔应力作用下的应力应变情况进行分析,分析插拔过程得到插拔力、接触压力、簧片变形量曲线。通过COMSOL对接触界面粗糙度对接触电阻的影响进行了分析,得到接触压力与接触面状态对接触电阻影响。通过ANSYS和COMSOL结合的方法,获得接触压力与接触电阻的关系曲线。模态分析得到接触件固有频率,进而得到振幅对接触压力的影响。仿真结果表明,在插针插入的过程中,最大应力位于簧片根部截面内侧开槽处。接触件粗糙平均高度越高,粗糙斜率越小时,接触电阻越大。当振动方向和振动频率保持不变时,最小接触压力随振幅的增大而减小。     

不同酚醛树脂对芳纶纸蜂窝性能的影响

为研究酚醛树脂对芳纶纸蜂窝性能的影响,本文采用两种不同的酚醛树脂制备芳纶纸蜂窝芯材,对所制备蜂窝芯材的压缩性能和剪切性能进行测试,同时结合蜂窝端面树脂分布观察、树脂与芳纶纸接触角测量等方法,分析了两种树脂所制备蜂窝芯材性能出现差异的原因,结果表明：树脂中溶剂水的挥发速度、树脂与芳纶纸之间的表面张力会影响树脂在蜂窝壁上的树脂分布;蜂窝芯材树脂含量相同时,其节点两侧的树脂胶柱有利于提高蜂窝芯材压缩强度,但树脂堆积在节点后会降低蜂窝壁厚,造成蜂窝的剪切强度和模量下降。     

改性双马来酰亚胺树脂预浸料性能研究

采用二烯丙基双酚A(Ortho-dially Bisphenol A,以下简称O-DABPA)对T型双马来酰亚胺(Bismaleimide,以下简称BMI)树脂进行改性,并用红外光谱(Fourier TransformInfrared,以下简称FT-IR)、差式扫描量热仪(Differential ScanningCalorimetry,以下简称DSC)对改性前后的树脂结构及固化反应进行测定,利用热熔预浸法对改性BMI树脂制备预浸料,考查了预浸料的力学性能及高温下的弯曲性能。结果表明,在175℃下二烯丙基双酚A和T型双马来酰亚胺树脂质量比为1∶1,反应时间为1 h时,改性BMI树脂制备的预浸料工艺性良好,单向板层间剪切强度为84.86 Mpa,在240℃时,弯曲强度及模量分别为1 326.41 MPa和120.31 GPa,强度保留率为76.73%。